you’ve got a chance, you might as well make full use of it.
A. Now that
B. After
C. Although
D. As soon as
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(答案→)A. Now that
B. After
C. Although
D. As soon as
解析：考查连词：A. Now that既然B. After在…后面，C. Although虽然D. As soon as一…就，句意：既然你有了机会，最好充分利用它。选A。